The dissertation concerns about the path loss calculation of Radio Frequency (RF) propagation models for 4G Long Term Evolution (LTE) Network to prefer the best Radio Frequency propagation model. The radio propagation models are very significant while planning of any wireless communication system. A comparative analysis between radio propagation models e.g. SUI model, Okumura model, Cost 231 Hata Model, Cost 231-Walfisch Ikegami and Ericsson 9999 model that would be used for outdoor propagation in LTE. The comparison and performance analysis has been made by using different geological environments e.g. urban, sub-urban and rural areas. The simulation scenario is made to calculate the lowest path loss in above defined environments by using selected frequency and height of base station antennas while keeping a constant distance between the transmitter and receiver antennas.